Magnetic Properties of Linear Chain Systems: Metamagnetism of Single Crystal Co(pyridine)2Cl2
Copyright © 1978 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Journal of Chemical Physics and may be found at http://dx.doi.org/10.1063/1.435658.
NOTE: At the time of publication, the author Richard B. Frankel was not yet affiliated with Cal Poly.
The metamagnetic behavior of the low temperature properties of single crystal Co(pyridine)2Cl2 is discussed. At 1.25 K oriented single crystals exhibit a two‐step metamagnetic transition at applied fields ∼0.8 and 1.6 kG along the b‐axis, a single transition at ∼0.7 kG for applied fields along the a∗ axis, and a single transition at ∼4.2 kG for an applied field along the c axis. Just above the transition fields a moment of 2μB/Co atom is measured for B0 parallel to the a∗ axis or b axis, and 0.4μB/Co atom is measured for the B0 parallel to the c axis. A large field dependent moment is observed at high fields. Many features of this compound closely mirror the behavior of CoCl2⋅2H2O. However, the Co(pyridine)2Cl2 has a much smaller interchain exchange, so that many features can be examined at lower fields. The basic features are consistent with a six‐sublattice model for the ordered antiferromagnetic system. Measurements of magnetic moment versus temperature show that Co(pyridine)2Cl2 does not obey a Curie–Weiss law even at relatively high temperatures.
S. Foner, Richard B. Frankel, W. M. Reiff, H. Wong, and Gary J. Long. "Magnetic Properties of Linear Chain Systems: Metamagnetism of Single Crystal Co(pyridine)2Cl2" Journal of Chemical Physics 68.11 (1978): 4781-4789.
Available at: http://works.bepress.com/rfrankel/3