Article
2-Carboxybenzenediazonium Chloride Monohydrate
Acta Crystallographica Section C: Crystal Structure Communications
Abstract
C7H5N2O2 +.Cl-H2O, Mr = 202.60, monoclinic, C2c, a = 25.62(3), b = 4.964(2), c = 14.900 (14)Å, β = 107.15 (4)°, V = 1811 (3)Å3, Z = 8, Dx = 1.486 g cm-3, λ(Mo Kα) = 0.71073 Å, µ = 3.9 cm-1, F(000) = 832, T = 298 K, R = 0.035 for 1275 observed reflections. The terminal N atom of the diazonium group is bent away from the carboxyl group. The N2 and the carboxyl group are on opposite sides of the best plane of the aromatic ring and, importantly, the carboxyl group is not fully conjugated with the aromatic ring but instead is rotated [12.3 (1)°] around the C-CO2 axis.
Department(s)
Chemistry
Keywords and Phrases
- Carbon Dioxide,
- Aromatic Rings,
- Carboxyl Groups,
- Aromatic Compounds
Document Type
Article - Journal
Document Version
Final Version
File Type
text
Language(s)
English
Rights
© 1993 International Union of Crystallography (IUCr), All rights reserved.
Publication Date
3-1-1993
Publication Date
01 Mar 1993
Disciplines
Citation Information
Christopher J. Horan, Charles Leslie Barnes and Rainer Glaser. "2-Carboxybenzenediazonium Chloride Monohydrate" Acta Crystallographica Section C: Crystal Structure Communications Vol. 49 Iss. 3 (1993) p. 507 - 509 ISSN: 0108-2701; 1600-5759 Available at: http://works.bepress.com/rainer-glaser/5/