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Article
Ce3-xMgxCo9: Transformation of a Pauli Paramagnet into a Strong Permanent Magnet
Ames Laboratory Accepted Manuscripts
  • Tej Lamichhane, Iowa State University and Ames Laboratory
  • Valentin Taufour, Ames Laboratory
  • Andriy Palasyuk, Ames Laboratory
  • Qisheng Lin, Ames Laboratory
  • Sergey Bud’ko, Iowa State University and Ames Laboratory
  • Paul C. Canfield, Iowa State University and Ames Laboratory
Publication Date
2-1-2018
Department
Ames Laboratory; Physics and Astronomy
Report Number
IS-J 9568
DOI
10.1103/PhysRevApplied.9.024023
Journal Title
Physical Review Applied
Abstract

We report on the synthesis of single-crystal and polycrystalline samples of Ce 3 − x Mg x Co 9 solid solution ( 0 ≤ x ≲ 1.4 ) and characterization of their structural and magnetic properties. The crystal structure remains rhombohedral in the whole composition range and Mg partially replaces Ce in the 6 c site of the CeCo 3 structure. Ferromagnetism is induced by Mg substitutions starting as low as x = 0.18 and reaching a Curie temperature as high as 450 K for x = 1.35 . Measurements on single crystals with x = 1.34 and T C = 440     K indicate an axial magnetic anisotropy with an anisotropy field of 6 T and a magnetization of 6     μ B / f . u . at 300 K. Coercicity is observed in the polycrystalline samples consistent with the observed axial magnetic anisotropy. Our discovery of ferromagnetism with large axial magnetic anisotropy induced by substituting a rare-earth element by Mg is a very promising result in the search of inexpensive permanent-magnet materials and suggests that other nonmagnetic phases, similar to CeCo 3 , may also conceal nearby ferromagnetic phases.

Language
en
Publisher
Iowa State University Digital Repository, Ames IA (United States)
Citation Information
Tej Lamichhane, Valentin Taufour, Andriy Palasyuk, Qisheng Lin, et al.. "Ce3-xMgxCo9: Transformation of a Pauli Paramagnet into a Strong Permanent Magnet" Vol. 9 Iss. 2 (2018) p. 024023
Available at: http://works.bepress.com/qisheng-lin/36/