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Faculty Selected Works of Nigam Rath
Article
Dicarbonyldichloridobis(Trimethylphosphane)Iron(Ii)–Carbonyldichloridotris(Trimethylphosphane)Iron(Ii)–Tetrahydrofuran (1/1/2)
Acta Crystallographica Section E-structure Reports Online (2011)
  • Nigam P. Rath, University of Missouri–St. Louis
  • Meghan Stouffer, University of Washington
  • Matthew K. Janssen, University of Washington
  • John R. Bleeke, University of Washington
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Abstract
The asymmetric unit of the title crystal, [FeCl2(C3H9P)3(CO)]·[FeCl2(C3H9P)2(CO)2]·2C4H8O, contains half mol­ecules of the two closely related FeII complexes lying on mirror planes and a tetra­hydro­furan solvent mol­ecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both FeII complex mol­ecules, a distorted octa­hedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C-H...O inter­actions are observed in the crystal structure.
Disciplines
Publication Date
April 15, 2011
DOI
10.1107/S1600536811009305
Publisher Statement
10.1107/S1600536811009305
Citation Information
Nigam P. Rath, Meghan Stouffer, Matthew K. Janssen and John R. Bleeke. "Dicarbonyldichloridobis(Trimethylphosphane)Iron(Ii)–Carbonyldichloridotris(Trimethylphosphane)Iron(Ii)–Tetrahydrofuran (1/1/2)" Acta Crystallographica Section E-structure Reports Online Vol. 67 Iss. 4 (2011) p. m462 - sup-10 ISSN: 1600-5368
Available at: http://works.bepress.com/nigam-rath/97/
Creative Commons license
Creative Commons License
This work is licensed under a Creative Commons CC_BY International License.