Oxidatively-Induced Aryl–F Bond formation from Pd(II) Fluorides

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Synthesis and Reactivity of Palladium(II) Fluoride Complexes Containing Nitrogen-Donor Ligands (with Jeff W. Kampf and Melanie S. Sanford), Dalton Transactions (2010)

This article describes the synthesis, characterization, and reactivity of palladium(II) fluoride complexes containing sp2 and...

 

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Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex (with Melanie S. Sanford), Journal of the American Chemical Society (2009)

This communication describes the rational design and synthesis of the remarkably stable PdIV monoaryl fluoride...

 

Aryl–CF3 Bond Formation from Aryl Pd(II)–CF3 Complexes via Pd(IV) Intermediates

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Mechanistic and Computational Studies of Oxidatively-Induced Aryl–CF3 Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation (with John B. Gary, Yingda Ye, and Melanie S. Sanford), Journal of the American Chemical Society (2011)

This article describes the rational design of first generation systems for oxidatively induced Aryl−CF3 bond-forming...

 

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Aryl C–CF3 Bond Forming Reductive Elimination from a Palladium(IV) Complex, Journal of the American Chemical Society (2010)

This communication describes oxidatively induced Ar−CF3 bond-forming reductive elimination from new PdII complexes of general...

 

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Oxidation of Catalytically Relevant Palladium Dimer with “CF3+: Formation and Reactivity of a Monomeric Palladium(IV) Aquo Complex (with Yingda Ye, Jeff W. Kampf, and Melanie S. Sanford), Journal of the American Chemical Society (2010)

The reaction of [(bzq)Pd(OAc)]2 (bzq = benzo[h]quinoline) with “CF3+” reagents to afford the monomeric PdIV...

 

C–H activation at High Oxidation State Palladium Complexes

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Aryl C–H Activation at Pd(IV) Centers (with Joy M. Racowski and Melanie S. Sanford), Journal of the American Chemical Society (2011)