Skip to main content
Article
Thermodynamic model for tricritical mixtures with application to ammonium
Journal Chemical Physics (1982)
  • Miron Kaufman
  • Robert B. Griffiths, Carnegie Mellon University
Abstract

Procedures are developed for using composition data in the three-phase region and variations of meniscus heights to determine the parameters needed to relate a classical thermodynamic model for fluid mixtures near tricritical points to actual experiments. In the case of the mixture ammonium sulfate + water + ethanol + benzene the result is a reasonably good fit to a variety of data, including light scattering measurements of intensity and correlation length. There is some evidence for deviations from the classical theory, but it is not unambiguous.

Disciplines
Publication Date
1982
Citation Information
Miron Kaufman and Robert B. Griffiths. "Thermodynamic model for tricritical mixtures with application to ammonium" Journal Chemical Physics Vol. 76 (1982)
Available at: http://works.bepress.com/miron_kaufman/19/