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Thermodynamic Model and Sum Rules for Three-Phase Coexistence near theTricritical Point in a Liquid Mixture
Physical Review Letters (1980)
  • Miron Kaufman
  • K. K. Bardhan
  • Robert B. Griffiths, Carnegie Mellon University
Abstract

Two sum rules for order-parameter susceptibilities are derived for the classical theory of the three-phase region near a tricritical point in ordinary liquid mixtures. The classical theory can also be fitted in a quantitative way to the composition data of Lang and Widom near the tricritical point in the mixture ethanol+ benzene+ water + ammonium sulfate.

Disciplines
Publication Date
January, 1980
Citation Information
Miron Kaufman, K. K. Bardhan and Robert B. Griffiths. "Thermodynamic Model and Sum Rules for Three-Phase Coexistence near theTricritical Point in a Liquid Mixture" Physical Review Letters Vol. 44 Iss. 7 (1980)
Available at: http://works.bepress.com/miron_kaufman/18/