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Relaxations in Ba2BiSbO6 Double Complex Perovskite Ceramics
Chemistry Faculty Research and Scholarship
  • Manoel Carvalho Castro, Jr.
  • Carlos William de Araujo Paschoal
  • Frank C Snyder
  • Michael W Lufaso, University of North Florida
Document Type
Article
Publication Date
11-15-2008
Disciplines
Abstract

The electric properties of the complex double perovskite Ba2BiSbO6 have been investigated using impedance spectroscopy in the frequency range from 1 Hz up to 1 MHz and in the temperature range from room temperature up to 560 K. There are two contributions to the electrical properties due to the grain and grain boundary. The oxygen vacancies play an important role in the conductivity and strongly increase the dielectric constant at high temperatures. The analysis of the frequency dependence of the conductivity clearly shows the structural phase transition of this compound near 515 K.

Comments

Originally published in Journal of Applied Physics 2008, 104, 104114

http://dx.doi.org/10.1063/1.3026654

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In Copyright
Citation Information
Manoel Carvalho Castro, Carlos William de Araujo Paschoal, Frank C Snyder and Michael W Lufaso. "Relaxations in Ba2BiSbO6 Double Complex Perovskite Ceramics" (2008)
Available at: http://works.bepress.com/michael_lufaso/6/