Article
Synthesis and X-ray Crystal Structure of [(C5Ph5)CrCl(μ-Cl)2Tl]2: An Example of the Rare M-X-TlI Linkage (X = Halide)
Chemistry Faculty Research
Document Type
Article
Publication Date
1-1-2007
Disciplines
Abstract
Reaction of solid TlCl with [(C5Ph5)CrCl(m-Cl)]2 in CH2Cl2 solvent yields the monomeric complex (C5Ph5)CrCl(m-Cl)2Tl in 80% isolated yield. The C5H5 and C5Me5 analogues do not react with TlCl suggesting a steric basis for the reaction of the C5Ph5 material. An X-ray crystal structure of [(C5Ph5)CrCl(m-Cl)2Tl]2•2CH2Cl2 was obtained.
Citation Information
Davis, K. B.; Harris, T. D.; Castellani, M. P.; Golen, J. A.; Rheingold, A. L., Synthesis and X-ray Crystal Structure of [(C5Ph5) CrCl (μ-Cl)2Tl]2: An Example of the Rare M−X−TlI Linkage (X=Halide). Organometallics 2007, 26 (19), 4843-4845.
This is the authors’ peer-reviewed manuscript. The version of record is available from the publisher at http://dx.doi.org/10.1021/om070231f. Copyright ©2007 American Chemical Society. All rights reserved.