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Article
Molecular and Electronic Structures of Metallaspiropentanes
Journal of the American Chemical Society (1985)
  • Mark S. Gordon
  • Philip Boudjouk
Abstract

Recent efforts in this laboratory have concentrated on synthesizing metallaspiropentane compounds (I) with M = C, Si, Ge, Sn, Ni, and Zn. To date, the molecule with M = Si and R = methyl has been successfully prepared, 1 while attempts to synthesize the corresponding carbon compound have not reached fruition. This paper presents initial ab initio calculations on the species with M = C and Si and with R = H. Geometries for all species were calculated with the

Disciplines
Publication Date
March, 1985
Publisher Statement
Reprinted (adapted) with permission from Journal of the American Chemical Society 107 (1985): 1439, doi:10.1021/ja00291a070. Copyright 1985 American Chemical Society.
Citation Information
Mark S. Gordon and Philip Boudjouk. "Molecular and Electronic Structures of Metallaspiropentanes" Journal of the American Chemical Society Vol. 107 Iss. 5 (1985)
Available at: http://works.bepress.com/mark_gordon/46/