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Article
A Theoretical Study of Some Reactions of HCSi-
Journal of the American Chemical Society (1991)
  • Michael W. Schmidt
  • Mark S. Gordon
Abstract

The ions HCSi- and H2CSiH- produced in recent flowing afterglow experiments are characterized structurally. Reactivity of the former ion with four molecules (C02, OCS, CS2, S02) is examined. Three of these species react in a sequence of intermediates of cyclic followed by acyclic structures, before reaching the final products.

Disciplines
Publication Date
July, 1991
Publisher Statement
Reprinted (adapted) with permission from Journal of the American Chemical Society 113 (1991): 5244, doi:10.1021/ja00014a016. Copyright 1991 American Chemical Society.
Citation Information
Michael W. Schmidt and Mark S. Gordon. "A Theoretical Study of Some Reactions of HCSi-" Journal of the American Chemical Society Vol. 113 Iss. 14 (1991)
Available at: http://works.bepress.com/mark_gordon/107/