"The Activation of Carbon-Fluorine Bonds by Oxidative Addition at Tungsten(O): An Electrochemical Study" by Andrea E. Russell

Selected Works of Mark R. Anderson

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The Activation of Carbon-Fluorine Bonds by Oxidative Addition at Tungsten(O): An Electrochemical Study

Journal of Electroanalytical Chemistry and Interfacial Electrochemistry (1989)

Andrea E. Russell, University of Utah
Carolyn E. Osterberg, University of Utah
Daniel J. Blackwood, University of Utah
Mark R. Anderson, Kennesaw State University
Thomas G. Richmond, University of Utah
Stanley Pons, University of Utah

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Abstract

We have investigated the anodic oxidation reactions of W(CO)4Et,F5 (I), where Et,F5 is the ligand N,N'-bis(pentafluorophenylidine)ethylenediamine, by cyclic voltammetry and infrared spectroelectrochemistry. The results in both acetonitrile and methylene chloride indicate an ece type mechanism, with the product of the first electron transfer stabilized by the more coordinating solvent.

Disciplines

Chemistry

Publication Date

January 10, 1989

Citation Information

Andrea E. Russell, Carolyn E. Osterberg, Daniel J. Blackwood, Mark R. Anderson, et al.. "The Activation of Carbon-Fluorine Bonds by Oxidative Addition at Tungsten(O): An Electrochemical Study" Journal of Electroanalytical Chemistry and Interfacial Electrochemistry Vol. 258 Iss. 1 (1989)
Available at: http://works.bepress.com/mark_anderson1/47/