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Article
Electrochemistry of C82: Relationship to Metallofullerene Electrochemistry
Journal of Electroanalytical Chemistry (1996)
  • Paul M. Burbank, Virginia Polytechnic Institute and State University
  • James R. Gibson, Virginia Polytechnic Institute and State University
  • Harry C. Dorn, Virginia Polytechnic Institute and State University
  • Mark R. Anderson, Kennesaw State University
Abstract

Square-wave voltammetry of C82 in pyridine solutions containing 0.10 M tetra-n-butyl ammonium perchlorate indicates that C82 is reduced in four one-electron steps prior to the onset of electrolyte decomposition. The first reduction occurs at potentials positive of the reported first reduction potentials of other empty cage fullerenes, and at approximately the same reported potential for the first reduction of the endohedral metallofullerenes La@C82 and Y@C82. No oxidations were observed for the C82 under these conditions.

Keywords
  • C82,
  • Metallofullerenes,
  • Electrochemistry,
  • Square-wave voltammetry
Disciplines
Publication Date
November, 1996
Citation Information
Paul M. Burbank, James R. Gibson, Harry C. Dorn and Mark R. Anderson. "Electrochemistry of C82: Relationship to Metallofullerene Electrochemistry" Journal of Electroanalytical Chemistry Vol. 417 Iss. 1-2 (1996)
Available at: http://works.bepress.com/mark_anderson1/35/