Contact printing (CP) is a common method for creating modified interfaces having two-dimensional patterns. The popularity of this method is due to the ease and low cost of this method. When printing an interfacial pattern with n-alkanethiols, the desired properties are those of a homogeneous, solution deposited monolayer. Patterning a surface, however, may cause defects to occur within the monolayer where two thiol domains meet. If large enough, the activity of these areas can dominate the electrochemical response. Creating patterned monolayer modified interfaces, therefore, may generate vast user defined domain boundaries that impact the electrochemical behavior of the modified interface and negatively impact the overall properties of the modified interface. This work describes the electrochemical properties of a homogeneous contact-printed monolayer.
- electrochemistry
Available at: http://works.bepress.com/mark_anderson1/10/