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Article
Characterizing kinetics near a first-order catalytic-poisoning transition
Physical Review Letters
  • James W. Evans, Iowa State University
  • M. S. Miesch, Iowa State University
Document Type
Article
Publication Date
1-1-1991
DOI
10.1103/PhysRevLett.66.833
Abstract
We conside the kinetics near a first-order poisoning transition for simple surface reaction models which exlude nonreactive desorption. Elucidation of the development and growth of the reactive steady state from a near-poisoned state is achieved via an ‘‘oxidation epidemic’’ analysis of the evolution of an empy patch embedded in the poisoned phase. Associated critical exponents vary strongly with reaction rate, and reflect slow kinetics. The increase in epidemic survival probability with initial patch size is smooth, and described by additional exponents, rather than indicating a critical size for survival.
Comments

This article is published as Evans, J. W., and M. S. Miesch. "Characterizing kinetics near a first-order catalytic-poisoning transition." Physical review letters 66, no. 6 (1991): 833, doi:10.1103/PhysRevLett.66.833. Posted with permission.

Copyright Owner
American Institute of Physics
Language
en
File Format
application/pdf
Citation Information
James W. Evans and M. S. Miesch. "Characterizing kinetics near a first-order catalytic-poisoning transition" Physical Review Letters Vol. 66 Iss. 6 (1991) p. 833 - 836
Available at: http://works.bepress.com/james-evans/147/