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Article
Absolute integrated cross sections for some O2 Herzberg I transitions near 248–249 nm
The Journal of Chemical Physics (1995)
  • Zhen-Chuan Bao, University of Michigan - Ann Arbor
  • Edward Yu, University of Michigan - Ann Arbor
  • John R. Baker, University of Michigan - Ann Arbor
Abstract

A frequency doubled tunable dye laser system with ∼0.4 cm−1 resolution was used to measure the integrated absorption cross sections of more than 20 rotational transitions in the O2 Herzberg I (A  3Σ+ u ←X  3Σ− g ) 8‐0 and 9‐0 vibrational bands near 248 nm and 249 nm. Oxygen pressures from 200 to 800 Torr and path lengths from 5 to 25 m were employed. The measured absorbances were fitted using a nonlinear least squares analysis and Beer’s Law to obtain absolute values for the individual transition integrated cross sections in good agreement with a recent spectral simulation and experimental data. By using the spectral simulation in conjunction with the present experimental results, total oscillator strengths in reasonable agreement with literature values were estimated for the 8‐0 and 9‐0 vibrational bands.

Publication Date
1995
Publisher Statement
Copyright 1995 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.
Citation Information
Zhen-Chuan Bao, Edward Yu and John R. Baker. "Absolute integrated cross sections for some O2 Herzberg I transitions near 248–249 nm" The Journal of Chemical Physics Vol. 103 Iss. 6 (1995)
Available at: http://works.bepress.com/edward_yu/1/