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Selected Works of David J. R. Brook
Article
Strong ferromagnetic metal-ligand exchange in a nickel bis(3,5-dipyridylverdazyl) complex
Chemical Communications (2010)
  • David J R Brook, San Jose State University
  • Cardius Richardson, San Jose State University
  • Benjamin C Haller, San Jose State University
  • Michael Hundley, Virginia Polytechnic Institute and State University
  • Gordon T Yee, Virginia Polytechnic Institute and State University
Link
Abstract
A new 1,5-dipyridyl verdazyl, synthesized from the corresponding dipyridyl hydrazone, coordinates nickel(II) to form a structurally characterized, pseudooctahedral complex analogous to Ni(terpy)22+. The unusually short Ni–verdazyl distance results in strong ferromagnetic exchange (JNi–rad = +300, Jrad–rad = +160 cm−1) between all three paramagnetic species along with a metal–ligand charge transfer band in the electronic spectrum.
Disciplines
Publication Date
2010
Publisher Statement
SJSU users: use the following link to login and access the article via SJSU databases
Citation Information
David J R Brook, Cardius Richardson, Benjamin C Haller, Michael Hundley, et al.. "Strong ferromagnetic metal-ligand exchange in a nickel bis(3,5-dipyridylverdazyl) complex" Chemical Communications Vol. 46 (2010)
Available at: http://works.bepress.com/david_brook/4/