In the first of a series of forthcoming publications, we present a panchromatic catalog of 102 visually-selected early-type galaxies (ETGs) from observations in the Early Release Science (ERS) program with the Wide Field Camera 3 (WFC3) on the Hubble Space Telescope (HST) of the Great Observatories Origins Deep Survey-South (GOODS-S) field. Our ETGs span a large redshift range, 0.35 < z < 1.5, with each redshift spectroscopically-confirmed by previous published surveys of the ERS field. We combine our measured WFC3 ERS and ACS GOODS-S photometry to gain continuous sensitivity from the rest-frame far-UV to near-IR emission for each ETG. The superior spatial resolution of the HST over this panchromatic baseline allows us to classify the ETGs by their small-scale internal structures, as well as their local environment. By fitting stellar population spectral templates to the broad-band photometry of the ETGs, we determine that the average masses of the ETGs are comparable to the characteristic stellar mass of massive galaxies, 11< log(M [Solar]) < 12. By transforming the observed photometry into the GALEX FUV and NUV, Johnson V, and SDSS g' and r' bandpasses we identify a noteworthy diversity in the rest-frame UV-optical colors and find the mean rest-frame (FUV-V)=3.5 and (NUV-V)=3.3, with 1$\sigma$ standard deviations approximately equal to 1.0. The blue rest-frame UV-optical colors observed for most of the ETGs are evidence for star-formation during the preceding gigayear, but no systems exhibit UV-optical photometry consistent with major recent (<~50 Myr) starbursts. Future publications which address the diversity of stellar populations likely to be present in these ETGs, and the potential mechanisms by which recent star-formation episodes are activated, are discussed.