Article
Studies of the Solid-Phase Pauson-Khand Reaction Selective in-situ Enone Reduction to 3-Azabicyclo[3.3.0]oct-anones
Tetrahedron Letters
Document Type
Article
Publication Date
3-26-1993
Pages
2087-2090
Publisher Name
Elsevier
Disciplines
Abstract
The Smit-Caple DSAC Pauson-Khand cyclization of a series of N-protected allyl propargyl amines in the absence of oxygen gave rise to formation of the saturated azabicyclo[3.3.0]octanones in excellent yields. Standard cyclization in air gave mixtures of saturated and unsaturated ketones.
Comments
Author Posting © Elsevier, 1993. This is the author's version of the work. It is posted here by permission of Elsevier for personal use, not for redistribution. The definitive version was published in Tetrahedron Letters, Volume 34, Issue 13, March 26, 1993. http://dx.doi.org/10.1016/S0040-4039(00)60352-0
Creative Commons License
Creative Commons Attribution-Noncommercial-No Derivative Works 3.0
Copyright Statement
© 1993 Elsevier
Citation Information
Daniel Becker and Daniel L. Flynn. "Studies of the Solid-Phase Pauson-Khand Reaction Selective in-situ Enone Reduction to 3-Azabicyclo[3.3.0]oct-anones" Tetrahedron Letters Vol. 34 Iss. 13 (1993) Available at: http://works.bepress.com/daniel_p_becker/13/