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Unpublished Paper
Distribution of Counterions Near Discretely Charged Planes and Rods
Europhysics Letters (2004)
  • M. L. Henle
  • Christian Santangelo
  • D. M. Patel
  • P. A. Pincus
Abstract

Realistic charged macromolecules are characterized by discrete (rather than homogeneous) charge distributions. We investigate the effects of surface charge discretization on the counterion distribution at the level of mean-field theory using a two-state model. Both planar and cylindrical geometries are considered; for the latter case, we compare our results to numerical solutions of the full Poisson-Boltzmann equation. We find that the discretization of the surface charge can cause enhanced localization of the counterions near the surface; for charged cylinders, counterion condensation can exceed Oosawa-Manning condensation.

Disciplines
Publication Date
2004
Comments
Prepublished version downloaded from ArXiv. Published version is located at http://iopscience.iop.org/0295-5075/66/2/284
Citation Information
M. L. Henle, Christian Santangelo, D. M. Patel and P. A. Pincus. "Distribution of Counterions Near Discretely Charged Planes and Rods" Europhysics Letters (2004)
Available at: http://works.bepress.com/christian_santangelo/14/