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Rare-Earth Iodides in Ionic Liquids:  The Crystal Structure of [SEt3]3[LnI6] (Ln = Nd, Sm)
Inorganic Chemistry (2005)
  • Anja V. Mudring
  • Arash Babai
Abstract

Crystals of [SEt3]3[LnI6] (Ln = Nd, Sm) were obtained by the reaction of LnI2 with the ionic liquid [SEt3][Tf2N] [Tf2N = bis(trifluoromethanesulfonyl)imide]. The compounds are characterized by octahedral [LnI6]3- units that are surrounded by a distorted cube of triethylsulfonium cations.

Publication Date
2005
Publisher Statement
Reprinted with permission from Inorg. Chem., 2005, 44 (23), pp 8168–8169. Copyright (2005) American Chemical Society.
Citation Information
Anja V. Mudring and Arash Babai. "Rare-Earth Iodides in Ionic Liquids:  The Crystal Structure of [SEt3]3[LnI6] (Ln = Nd, Sm)" Inorganic Chemistry Vol. 44 Iss. 23 (2005)
Available at: http://works.bepress.com/anja_mudring/55/