Article
Lanthanide Coordination Polymers with Tetrafluoroterephthalate as a Bridging Ligand: Thermal and Optical Properties
Inorganic Chemistry
(2012)
Abstract
Seven new coordination polymers ∞2[Ln(tfBDC)(NO3)(DMF)2]·DMF (Ln3+ = Ce, Pr, Nd, Sm, Dy, Er, Yb) with the perfluorinated linker ligand tetrafluoroterephthalate (tfBDC2−) have been synthesized. Their crystal structures consist of layers (44 nets) weakly bound by van der Waals interactions. In addition, differential thermal analysis/thermogravimetry (DTA/TG) curves, as well as absorption and emission spectra, have been recorded for all compounds.
Disciplines
Publication Date
2012
Publisher Statement
Reprinted with permission from Inorg. Chem., 2012, 51 (8), pp 4679–4688. Copyright (2012) American Chemical Society.
Citation Information
Christiane Seidel, Chantal Lorbeer, Joanna Cyninska, Anja V. Mudring, et al.. "Lanthanide Coordination Polymers with Tetrafluoroterephthalate as a Bridging Ligand: Thermal and Optical Properties" Inorganic Chemistry Vol. 51 Iss. 8 (2012) Available at: http://works.bepress.com/anja_mudring/19/