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Article
Resistivity, thermopower and the correlation to infrared active vibrations of Mn1.56Co0.96Ni0.48O4 spinel films sputtered in an oxygen partial pressure series
Journal of Applied Physics (1999)
  • Rand Dannenberg
  • S. Baliga
  • R. J. Gambino, State University of New York at Stony Brook
  • Alexander H. King, State University of New York at Stony Brook
  • A. P. Doctor
Abstract

Mn1.56Co0.96Ni0.48O4 spinel was sputter deposited using a series of oxygen partial pressures. Electrical resistivity versus temperature and thermopower versus temperature measurements at each oxygen partial pressure were made. The variations of the thermopower and resistivity with oxygen partial pressure are consistent with a change in the ratio of Mn3+ to Mn4+ cations, which occurs due to changes of oxygen content of the material. The weak temperature dependence of the thermopower indicates small polaron hopping is the charge transport mechanism. Combining the models of Mott and Schnakenberg to analyze the transport data, we find that the Debye temperature (or frequency) is an increasing function of the oxygen partial pressure used during sputtering. The calculated shift in the Debye frequency from the resistivity is consistent with the observed shift in the fundamental infrared active lattice vibrations from Fourier transform infrared spectroscopy and Raman spectroscopy.

Keywords
  • manganese compounds,
  • cobalt compounds,
  • nickel compounds,
  • semiconductor thin films,
  • semiconductor materials,
  • electrical resistivity,
  • thermoelectric power,
  • sputtered coatings,
  • infrared spectra,
  • Fourier transform spectra,
  • Raman spectra,
  • small polaron conduction,
  • hopping conduction,
  • Debye temperature
Publication Date
1999
Publisher Statement
Copyright 1999 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Journal of Applied Physics 86 (1999): 514–523 and may be found at http://dx.doi.org/10.1063/1.370760.
Citation Information
Rand Dannenberg, S. Baliga, R. J. Gambino, Alexander H. King, et al.. "Resistivity, thermopower and the correlation to infrared active vibrations of Mn1.56Co0.96Ni0.48O4 spinel films sputtered in an oxygen partial pressure series" Journal of Applied Physics Vol. 86 Iss. 1 (1999)
Available at: http://works.bepress.com/alex_king/34/